SAFETY DATA SHEET
Date Issued : 06/29/2017
SDS No : M-3190 REV 1 PART A
Date Revised : 08/12/2020
Revision No : 1
M-3190 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: M-3190 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5 4. FIRST AID MEASURES EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical advice/attention if irritation develops. SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash develops. Wash clothing before reuse. INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person. INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops. NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate- containing vapor. FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff from fire control methods to sewers or waterways. FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of Page 1 of 6 unmanned hose holders or monitor nozzles for fighting large fires. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a container for disposal according to local/national regulations. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Do not discharge into drains, surface waters, or groundwater. GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details. RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors. HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a manner consistent with good industrial/manufacturing techniques and practices. STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. STORAGE TEMPERATURE: 65-80 F (18-27 C) SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 2 of 6 M-3190 REV 1 PART A EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS Chemical Name Type ppmmg/m 3 Polyurethane prepolymer OSHA PEL TWA - - STEL - - ACGIH TLV TWA - - STEL - - NIOSH REL TWA - - STEL - - 1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear OSHA PEL TWA - - STEL - - ACGIH TLV TWA - - STEL - - NIOSH REL TWA - - STEL - - Toluene diisocyanate OSHA PEL TWA - - STEL - - ACGIH TLV TWA 0.005 - STEL0.02 - NIOSH REL TWA - - STEL - - ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent. SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection. RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134). PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical Protective Clothing" published by ACGIH. WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate work area should be prohibited. Wash hands before eating. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is important. Follow all label precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Viscous liquid ODOR: Slight COLOR: Pale yellow Page 3 of 6 M-3190 REV 1 PART A pH: No data available FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slightly with water
SPECIFIC GRAVITY: 1.067 (water=1) at 25 C (77 F)
VISCOSITY #1: 4450 Centipoise at 25 C (77 F)
(VOC): < 1.9 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions. STABILITY: This product is stable under normal ambient conditions of temperature and pressure. CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions. POSSIBILITY OF HAZARDOUS REACTIONS: No data available HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate- containing vapor. INCOMPATIBLE MATERIALS: Water, alcohols, and oxidizing agents. 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50 Polyurethane prepolymer No data available No data available No data available 1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear > 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Toluene diisocyanate
3360 mg/kg Rat 10000 mg/kg
Rabbit
0.35 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status IARC Status
Toluene diisocyanate 2 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
Page 4 of 6
M-3190 REV 1 PART A

CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Toluene diisocyanate < 0.1 100 lbs. Naphthalene < 0.001 100 lbs. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification. TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements. CLEAN AIR ACT Chemical Name Wt.% CAS Toluene diisocyanate < 0.126471-62-5 OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA ) 29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this product are considered highly hazardous by OSHA. CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov. Chemical Name Wt.% Listed Toluene diisocyanate < 0.1 Cancer Naphthalene < 0.001 Cancer Ethyl acrylate < 0.0001 Cancer OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. CANADA WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the hazard criteria of the CPR and the SDS contains all the information required by the CPR. Page 5 of 6 M-3190 REV 1 PART A DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL). GENERAL COMMENTS: No data available 16. OTHER INFORMATION REASON FOR ISSUE: Revision Date Revised: 08/12/2020 REVISION SUMMARY: This SDS replaces the 06/29/2017 SDS. HMIS RATING HEALTH 1 FLAMMABILITY 1 PHYSICAL HAZARD 0 PERSONAL PROTECTION X NFPA CODES 1 1 0 HMIS RATINGS NOTES: Personal Protection: See Section 8 MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal responsibility for use or reliance upon this data. Page 6 of 6 M-3190 REV 1 PART A SAFETY DATA SHEET Date issued : 06/29/2017 SDS number : M-3190 REV 1 PART B Date revised : 08/12/2020 Revision number : 1 M-3190 REV 1 PART B 1. Identification Product identifier: M-3190 REV 1 PART B Relevant identified uses: Polyurethane curative Manufacturer / Supplier Emergency telephone number (24 hour) BJB Enterprises, Inc. 14791 Franklin Avenue Tustin, CA 92780 Emergency Phone: (714) 734-8450 CHEMTREC (USA & Canada): (800) 424-9300 or (703) 527-3887 CCN# 2820 2. Hazard identification Classification of the substance or mixture Health hazards: Acute Toxicity (Oral), Category 4 Skin Sensitization, Category 1 Environmental hazards: Acute Hazards to the Aquatic Environment, Category 2 Chronic Hazards to the Aquatic Environment, Category 3 Label elements Exclamation mark Signal word: WARNING Hazard statement(s) H302: Harmful if swallowed. H317: May cause an allergic skin reaction. H401: Toxic to aquatic life. H412: Harmful to aquatic life with long lasting effects. Precautionary statement(s) Prevention: P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves. P273: Avoid release to the environment. Response: P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell. P330: Rinse mouth. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P391: Collect spillage. Page 1 of 5 Disposal: P501: Dispose of contents/container in accordance with local/regional/national/international regulations. 3. Composition/information on ingredients Chemical name % w/wCAS No. Polyether polyol mixture 40 - 70Proprietary 1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 10 - 30102093-68-5 1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 5 - 10104983-85-9 4. First-aid measures Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get medical advice/attention if irritation develops. Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash develops. Wash clothing before reuse. Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops. Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. 5. Fire-fighting measures Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam. Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides. Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff from fire control methods to sewers or waterways. Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned hose holders or monitor nozzles for fighting large fires. 6. Accidental release measures Small spill: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills with a decontaminant. Large spill: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15). Environmental precautions Water spill: Do not discharge into drains, surface waters, or groundwater. General procedures: Refer to section 8 of SDS for personal protection details. Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary. 7. Handling and storage General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors. Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a manner consistent with good industrial/manufacturing techniques and practices. Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Storage temperature: 65-80 F (18-27 C) Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions. Page 2 of 5 M-3190 REV 1 PART B 8. Exposure controls/personal protection Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Individual protection measures, such as personal protective equipment Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent. Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection. Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134). Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical Protective Clothing" published by ACGIH. Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate work area should be prohibited. Wash hands before eating. Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is important. Follow all label precautions. 9. Physical and chemical properties Physical state: Liquid Color: Amber Odor: Slight amine pH: No data available Initial boiling point and boiling range: No data available Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.082 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 1100 Centipoise at 25 C (77 F)
Percent volatiles: 0.05
VOC content: < 0.55 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. Stability and reactivity Reactivity: Hazardous reactions will not occur under normal transport or storage conditions. Chemical stability: This product is stable under normal ambient conditions of temperature and pressure. Conditions to avoid: High temperatures, moisture, and freezing conditions. Possibility of hazardous reactions: None Known Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides. Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents. 11. Toxicological information Acute toxicity Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l Polyether polyol mixture No data available No data available No data available 1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available 1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available Page 3 of 5 M-3190 REV 1 PART B Skin corrosion / irritation: No data available Serious eye damage / irritation: No data available Respiratory or skin sensitization: May cause sensitization by skin contact. Germ cell mutagenicity: No data available Carcinogenicity Notes: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity: No data available Specific Target Organ Toxicity - single exposure: No data available Specific Target Organ Toxicity - repeated exposure: No data available Aspiration hazard: No data available 12. Ecological information Ecotoxicological information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the environment. Persistence and degradability: No data available Bioaccumulative potential: No data available Other adverse effects: This product may cause risk of hazardous effects to the environment. Mobility in soil: No data available 13. Disposal considerations Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. 14. Transport information USA Department of Transport Regulations (DOT): Not Regulated ICAO - air: Not Regulated IMDG - sea: Not Regulated 15. Regulatory information UNITED STATES SARA Section 311/312 Hazard Categories 311/312 Health hazards: Refer to Section 2 for hazard classification. 313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. CERCLA Hazardous Substances and Reportable Quantities (RQ) CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). TSCA (The Toxic Substances Control Act) TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification. TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements. Occupational safety and health administration (osha) 29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly hazardous by OSHA. California Proposition 65: This product does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other reproductive harm. USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. Page 4 of 5 M-3190 REV 1 PART B CANADA WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the information required by the CPR. Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL). 16. Other information Reason for issue: Revision Date revised: 08/12/2020 Revision summary: This SDS replaces the 06/29/2017 SDS. HMIS rating Health 2 Flammability 1 Physical hazard 0 Personal protection X NFPA codes 1 2 0 HMIS ratings notes: Personal Protection: See Section 8 Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal responsibility for use or reliance upon this data. Page 5 of 5 M-3190 REV 1 PART B